1H NMR Data
proton
mult
CDCl 3
(CD3) 2CO
(CD3) 2SO
C 6D 6
CD 3CN
CD 3OD
D 2O
solvent residual peak 7.26 2.05 2.50 7.16 1.94 3.31 4.79
H 2O s 1.56 2.84a 3.33a 0.40 2.13 4.87
acetic acid CH 3 s 2.10 1.96 1.91 1.55 1.96 1.99 2.08 acetone CH 3 s 2.17 2.09 2.09 1.55 2.08 2.15 2.22 acetonitrile CH 3 s 2.10 2.05 2.07 1.55 1.96 2.03 2.06 benzene CH s 7.36 7.36 7.37 7.15 7.37 7.33
tert -butyl alcohol CH3 s 1.28 1.18 1.11 1.05 1.16 1.40 1.24
OH c s 4.19 1.55 2.18
tert -butyl methyl ether CCH3 s 1.19 1.13 1.11 1.07 1.14 1.15 1.21
OCH 3 s 3.22 3.13 3.08 3.04 3.13 3.20 3.22
BHT b ArH s 6.98 6.96 6.87 7.05 6.97 6.92
OH c s 5.01 6.65 4.79 5.20 ArCH 3 s 2.27 2.22 2.18 2.24 2.22 2.21 ArC(CH3) 3 s 1.43 1.41 1.36 1.38 1.39 1.40
chloroform CH s 7.26 8.02 8.32 6.15 7.58 7.90 cyclohexane CH 2 s 1.43 1.43 1.40 1.40 1.44 1.45 1,2-dichloroethane CH 2 s 3.73 3.87 3.90 2.90 3.81 3.78 dichloromethane CH 2 s 5.30 5.63 5.76 4.27 5.44 5.49
diethyl ether CH 3 t, 7 1.21 1.11 1.09 1.11 1.12 1.18 1.17
CH 2 q, 7 3.48 3.41 3.38 3.26 3.42 3.49 3.56
diglyme CH 2 m 3.65 3.56 3.51 3.46 3.53 3.61 3.67
CH 2 m 3.57 3.47 3.38 3.34 3.45 3.58 3.61 OCH 3 s 3.39 3.28 3.24 3.11 3.29 3.35 3.37
1,2-dimethoxyethane CH 3 s 3.40 3.28 3.24 3.12 3.28 3.35 3.37
CH 2 s 3.55 3.46 3.43 3.33 3.45 3.52 3.60
dimethylacetamide CH 3CO s 2.09 1.97 1.96 1.60 1.97 2.07 2.08
NCH 3 s 3.02 3.00 2.94 2.57 2.96 3.31 3.06 NCH 3 s 2.94 2.83 2.78 2.05 2.83 2.92 2.90
dimethylformamide CH s 8.02 7.96 7.95 7.63 7.92 7.97 7.92
CH 3 s 2.96 2.94 2.89 2.36 2.89 2.99 3.01 CH 3 s 2.88 2.78 2.73 1.86 2.77 2.86 2.85
dimethyl sulfoxide CH 3 s 2.62 2.52 2.54 1.68 2.50 2.65 2.71 dioxane CH 2 s 3.71 3.59 3.57 3.35 3.60 3.66 3.75 ethanol CH 3 t, 7 1.25 1.12 1.06 0.96 1.12 1.19 1.17
CH 2 q, 7d 3.72 3.57 3.44 3.34 3.54 3.60 3.65 OH s c,d 1.32 3.39 4.63 2.47
ethyl acetate CH 3CO s 2.05 1.97 1.99 1.65 1.97 2.01 2.07
C H 2CH 3 q, 7 4.12 4.05 4.03 3.89 4.06 4.09 4.14 CH 2C H 3 t, 7 1.26 1.20 1.17 0.92 1.20 1.24 1.24
ethyl methyl ketone CH 3CO s 2.14 2.07 2.07 1.58 2.06 2.12 2.19
C H 2CH 3 q, 7 2.46 2.45 2.43 1.81 2.43 2.50 3.18 CH 2C H 3 t, 7 1.06 0.96 0.91 0.85 0.96 1.01 1.26
ethylene glycol CH s e 3.76 3.28 3.34 3.41 3.51 3.59 3.65
f “grease” CH 3 m 0.86 0.87 0.92 0.86 0.88
CH 2 br s 1.26 1.29 1.36 1.27 1.29
n -hexane CH 3 t 0.88 0.88 0.86 0.89 0.89 0.90
CH 2 m 1.26 1.28 1.25 1.24 1.28 1.29
HMPA g CH 3 d, 9.5 2.65 2.59 2.53 2.40 2.57 2.64 2.61 methanol CH 3 s h 3.49 3.31 3.16 3.07 3.28 3.34 3.34
c,h OH s 1.09 3.12 4.01 2.16
nitromethane CH 3 s 4.33 4.43 4.42 2.94 4.31 4.34 4.40 n -pentane CH 3 t, 7 0.88 0.88 0.86 0.87 0.89 0.90
CH 2 m 1.27 1.27 1.27 1.23 1.29 1.29
2-propanol CH 3 d, 6 1.22 1.10 1.04 0.95 1.09 1.50 1.17
CH sep, 6 4.04 3.90 3.78 3.67 3.87 3.92 4.02
pyridine CH(2) m 8.62 8.58 8.58 8.53 8.57 8.53 8.52
CH(3) m 7.29 7.35 7.39 6.66 7.33 7.44 7.45 CH(4) m 7.68 7.76 7.79 6.98 7.73 7.85 7.87
i silicone greaseCH 3 s 0.07 0.13 0.29 0.08 0.10
tetrahydrofuran CH 2 m 1.85 1.79 1.76 1.40 1.80 1.87 1.88
CH 2O m 3.76 3.63 3.60 3.57 3.64 3.71 3.74
toluene CH 3 s 2.36 2.32 2.30 2.11 2.33 2.32
CH(o/p) m 7.17 7.1-7.2 7.18 7.02 7.1-7.3 7.16 CH(m ) m 7.25 7.1-7.2 7.25 7.13 7.1-7.3 7.16
triethylamine CH 3 t,7 1.03 0.96 0.93 0.96 0.96 1.05 0.99
CH 2 q, 7 2.53 2.45 2.43 2.40 2.45 2.58 2.57
13C NMR Data a
CDCl 3
solvent signals
CO
CH 3
acetone
CO CH 3
acetonitrile
CN CH 3
benzene
CH
tert -butyl alcohol C
3
tert -butyl methyl ether CH
OCH 3 acetic acid
77.16 ( 0.06 175.99 20.81 207.07 30.92 116.43 1.89 128.37 69.15 31.25 49.45 (CD3) 2CO 29.84 ( 0.01 206.26 ( 0.13 172.31 20.51 205.87 30.60 117.60 1.12 129.15 68.13 30.72 49.35 (CD3) 2SO
C 6D 6
CD 3CN 1.32 ( 0.02 118.26 ( 0.02 173.21 20.73 207.43 30.91 118.26 1.79 129.32 68.74 30.68 49.52 CD 3OD 49.00(0.01 175.11 20.56 209.67 30.67 118.06 0.85 129.34 69.40 30.91 49.66 177.21 21.03 215.94 30.89 119.68 1.47 D 2O
39.52 ( 0.06 128.06 ( 0.02 171.93 20.95 206.31 30.56 117.91 1.03 128.30 66.88 30.38 48.70 175.82 20.37 204.43 30.14 116.02 0.20 128.62 68.19 30.47 49.19
70.36 30.29 49.37 BHT
chloroform
cyclohexane
1,2-dichloroethane dichloromethane diethyl ether diglyme
1,2-dimethoxyethane dimethylacetamide
dimethylformamide
dimethyl sulfoxide
dioxane ethanol ethyl acetate
ethyl methyl ketone ethylene glycol
“grease” n -hexane HMPA b
methanol
nitromethane n -pentane 2-propanol
pyridine
silicone grease
tetrahydrofuran toluene
triethylamine
C 72.87 C C H 3
26.99 C(1) 151.55 C(2) 135.87 CH(3) 125.55 C(4) 128.27 CH 3Ar 21.20 C H 3C 30.33 C 34.25 CH 77.36 CH 2 26.94 CH 2 43.50 CH 2 53.52 CH 3
15.20 CH 2
65.91 CH 3 59.01 CH 2
70.51 CH
2
71.90 CH 3 59.08 CH 2
71.84 CH 3 21.53 CO 171.07 NCH 3
35.28 NCH 3 38.13 CH 162.62 CH 3
36.50 CH 3 31.45 CH 3
40.76 CH 2 67.14 CH 3
18.41 CH 2
58.28 C H 3CO 21.04 CO 171.36 CH 2
60.49 CH
3
14.19 C H 3CO 29.49 CO 209.56 C H 2CH 3
36.89 CH 2C H 3 7.86 CH 2
63.79 CH 2 29.76 CH 3
14.14 CH 2(2) 22.70 CH 2(3) 31.64 CH 3 36.87 CH 3 50.41 CH 3 62.50 CH 3
14.08 CH 2(2) 22.38 CH 2(3) 34.16 CH 3 25.14 CH 64.50 CH(2) 149.90 CH(3) 123.75 CH(4) 135.96 CH 3
1.04 CH 2
25.62 CH 2O 67.97 CH 3 21.46 C(i ) 137.89 CH(o ) 129.07 CH(m ) 128.26 CH(p ) 125.33 CH 3 11.61 CH 2
46.25
72.81 72.04 27.24 26.79 152.51 151.47 138.19 139.12 129.05 127.97 126.03 124.85 21.31 20.97 31.61 31.25 35.00 34.33 79.19 79.16 27.51 26.33 45.25 45.02 54.95 54.84 15.78 15.12 66.12 62.05 58.77 57.98 71.03 69.54 72.63 71.25 58.45 58.01 72.47 17.07 21.51 21.29 170.61 169.54 34.89 37.38 37.92 34.42 162.79 162.29 36.15 35.73 31.03 30.73 41.23 40.45 67.60 66.36 18.89 18.51 57.72 56.07 20.83 20.68 170.96 170.31 60.56 59.74 14.50 14.40 29.30 29.26 208.30 208.72 36.75 35.83 8.03 7.61 64.26 62.76 30.73 29.20 14.34 13.88 23.28 22.05 32.30 30.95 37.04 36.42 49.77 48.59 63.21 63.28 14.29 13.28 22.98 21.70 34.83 33.48 25.67 25.43 63.85 64.92 150.67 149.58 124.57 123.84 136.56 136.05 1.40 26.15 25.14 68.07 67.03 21.46 20.99 138.48 137.35 129.76 128.88 129.03 128.18 126.12 125.29 12.49 11.74 47.07
45.74
72.40 73.17 27.09 27.28 152.05 152.42 136.08 138.13 128.52 129.61 125.83 126.38 21.40 21.23 31.34 31.50 34.35 35.05 77.79 79.17 27.23 27.63 43.59 45.54 53.46 55.32 15.46 15.63 65.94 66.32 58.66 58.90 70.87 70.99 72.35 72.63 58.68 58.89 72.21 72.47 21.16 21.76 169.95 171.31 34.67 35.17 37.03 38.26 162.13 163.31 35.25 36.57 30.72 31.32 40.03 41.31 67.16 67.72 18.72 18.80 57.86 57.96 20.56 21.16 170.44 171.68 60.21 60.98 14.19 14.54 28.56 29.60 206.55 209.88 36.36 37.09 7.91 8.14 64.34 64.22 30.21 30.86 14.32 14.43 23.04 23.40 31.96 32.36 36.88 37.10 49.97 49.90 61.16 63.66 14.25 14.37 22.72 23.08 34.45 34.89 25.18 25.55 64.23 64.30 150.27 150.76 123.58 127.76 135.28 136.89 1.38 25.72 26.27 67.80 68.33 21.10 21.50 137.91 138.90 129.33 129.94 128.56 129.23 125.68 126.28 12.35 12.38 46.77
47.10
74.32 75.62 27.22 26.60
152.85 139.09 129.49 126.11 21.38 31.15 35.36 79.44 27.96 45.11 54.78 15.46
14.77 66.88 66.42 59.06 58.67 71.33 70.05 72.92 71.63 59.06 58.67 72.72 71.49 21.32 21.09 173.32 174.57 35.50 35.03 38.43 38.76 164.73 165.53 36.89 37.54 31.61 32.03 40.45 39.39 68.11 67.19 18.40 17.47 58.26 58.05 20.88 21.15 172.89 175.26 61.50 62.32 14.49 13.92 29.39 29.49 212.16 218.43 37.34 37.27 8.09 7.87 64.30 63.17
31.29 14.45 23.68 32.73 37.00 36.46 49.86 49.50c 63.08 63.22
14.39 23.38 35.30 25.27
24.38 64.71 64.88 150.07 149.18 125.53 125.12 138.35 138.27 2.10 26.48 25.67 68.83 68.68
21.50 138.85 129.91 129.20 126.29 11.09
9.07 46.96
47.19
1H NMR Data
proton
mult
CDCl 3
(CD3) 2CO
(CD3) 2SO
C 6D 6
CD 3CN
CD 3OD
D 2O
solvent residual peak 7.26 2.05 2.50 7.16 1.94 3.31 4.79
H 2O s 1.56 2.84a 3.33a 0.40 2.13 4.87
acetic acid CH 3 s 2.10 1.96 1.91 1.55 1.96 1.99 2.08 acetone CH 3 s 2.17 2.09 2.09 1.55 2.08 2.15 2.22 acetonitrile CH 3 s 2.10 2.05 2.07 1.55 1.96 2.03 2.06 benzene CH s 7.36 7.36 7.37 7.15 7.37 7.33
tert -butyl alcohol CH3 s 1.28 1.18 1.11 1.05 1.16 1.40 1.24
OH c s 4.19 1.55 2.18
tert -butyl methyl ether CCH3 s 1.19 1.13 1.11 1.07 1.14 1.15 1.21
OCH 3 s 3.22 3.13 3.08 3.04 3.13 3.20 3.22
BHT b ArH s 6.98 6.96 6.87 7.05 6.97 6.92
OH c s 5.01 6.65 4.79 5.20 ArCH 3 s 2.27 2.22 2.18 2.24 2.22 2.21 ArC(CH3) 3 s 1.43 1.41 1.36 1.38 1.39 1.40
chloroform CH s 7.26 8.02 8.32 6.15 7.58 7.90 cyclohexane CH 2 s 1.43 1.43 1.40 1.40 1.44 1.45 1,2-dichloroethane CH 2 s 3.73 3.87 3.90 2.90 3.81 3.78 dichloromethane CH 2 s 5.30 5.63 5.76 4.27 5.44 5.49
diethyl ether CH 3 t, 7 1.21 1.11 1.09 1.11 1.12 1.18 1.17
CH 2 q, 7 3.48 3.41 3.38 3.26 3.42 3.49 3.56
diglyme CH 2 m 3.65 3.56 3.51 3.46 3.53 3.61 3.67
CH 2 m 3.57 3.47 3.38 3.34 3.45 3.58 3.61 OCH 3 s 3.39 3.28 3.24 3.11 3.29 3.35 3.37
1,2-dimethoxyethane CH 3 s 3.40 3.28 3.24 3.12 3.28 3.35 3.37
CH 2 s 3.55 3.46 3.43 3.33 3.45 3.52 3.60
dimethylacetamide CH 3CO s 2.09 1.97 1.96 1.60 1.97 2.07 2.08
NCH 3 s 3.02 3.00 2.94 2.57 2.96 3.31 3.06 NCH 3 s 2.94 2.83 2.78 2.05 2.83 2.92 2.90
dimethylformamide CH s 8.02 7.96 7.95 7.63 7.92 7.97 7.92
CH 3 s 2.96 2.94 2.89 2.36 2.89 2.99 3.01 CH 3 s 2.88 2.78 2.73 1.86 2.77 2.86 2.85
dimethyl sulfoxide CH 3 s 2.62 2.52 2.54 1.68 2.50 2.65 2.71 dioxane CH 2 s 3.71 3.59 3.57 3.35 3.60 3.66 3.75 ethanol CH 3 t, 7 1.25 1.12 1.06 0.96 1.12 1.19 1.17
CH 2 q, 7d 3.72 3.57 3.44 3.34 3.54 3.60 3.65 OH s c,d 1.32 3.39 4.63 2.47
ethyl acetate CH 3CO s 2.05 1.97 1.99 1.65 1.97 2.01 2.07
C H 2CH 3 q, 7 4.12 4.05 4.03 3.89 4.06 4.09 4.14 CH 2C H 3 t, 7 1.26 1.20 1.17 0.92 1.20 1.24 1.24
ethyl methyl ketone CH 3CO s 2.14 2.07 2.07 1.58 2.06 2.12 2.19
C H 2CH 3 q, 7 2.46 2.45 2.43 1.81 2.43 2.50 3.18 CH 2C H 3 t, 7 1.06 0.96 0.91 0.85 0.96 1.01 1.26
ethylene glycol CH s e 3.76 3.28 3.34 3.41 3.51 3.59 3.65
f “grease” CH 3 m 0.86 0.87 0.92 0.86 0.88
CH 2 br s 1.26 1.29 1.36 1.27 1.29
n -hexane CH 3 t 0.88 0.88 0.86 0.89 0.89 0.90
CH 2 m 1.26 1.28 1.25 1.24 1.28 1.29
HMPA g CH 3 d, 9.5 2.65 2.59 2.53 2.40 2.57 2.64 2.61 methanol CH 3 s h 3.49 3.31 3.16 3.07 3.28 3.34 3.34
c,h OH s 1.09 3.12 4.01 2.16
nitromethane CH 3 s 4.33 4.43 4.42 2.94 4.31 4.34 4.40 n -pentane CH 3 t, 7 0.88 0.88 0.86 0.87 0.89 0.90
CH 2 m 1.27 1.27 1.27 1.23 1.29 1.29
2-propanol CH 3 d, 6 1.22 1.10 1.04 0.95 1.09 1.50 1.17
CH sep, 6 4.04 3.90 3.78 3.67 3.87 3.92 4.02
pyridine CH(2) m 8.62 8.58 8.58 8.53 8.57 8.53 8.52
CH(3) m 7.29 7.35 7.39 6.66 7.33 7.44 7.45 CH(4) m 7.68 7.76 7.79 6.98 7.73 7.85 7.87
i silicone greaseCH 3 s 0.07 0.13 0.29 0.08 0.10
tetrahydrofuran CH 2 m 1.85 1.79 1.76 1.40 1.80 1.87 1.88
CH 2O m 3.76 3.63 3.60 3.57 3.64 3.71 3.74
toluene CH 3 s 2.36 2.32 2.30 2.11 2.33 2.32
CH(o/p) m 7.17 7.1-7.2 7.18 7.02 7.1-7.3 7.16 CH(m ) m 7.25 7.1-7.2 7.25 7.13 7.1-7.3 7.16
triethylamine CH 3 t,7 1.03 0.96 0.93 0.96 0.96 1.05 0.99
CH 2 q, 7 2.53 2.45 2.43 2.40 2.45 2.58 2.57
13C NMR Data a
CDCl 3
solvent signals
CO
CH 3
acetone
CO CH 3
acetonitrile
CN CH 3
benzene
CH
tert -butyl alcohol C
3
tert -butyl methyl ether CH
OCH 3 acetic acid
77.16 ( 0.06 175.99 20.81 207.07 30.92 116.43 1.89 128.37 69.15 31.25 49.45 (CD3) 2CO 29.84 ( 0.01 206.26 ( 0.13 172.31 20.51 205.87 30.60 117.60 1.12 129.15 68.13 30.72 49.35 (CD3) 2SO
C 6D 6
CD 3CN 1.32 ( 0.02 118.26 ( 0.02 173.21 20.73 207.43 30.91 118.26 1.79 129.32 68.74 30.68 49.52 CD 3OD 49.00(0.01 175.11 20.56 209.67 30.67 118.06 0.85 129.34 69.40 30.91 49.66 177.21 21.03 215.94 30.89 119.68 1.47 D 2O
39.52 ( 0.06 128.06 ( 0.02 171.93 20.95 206.31 30.56 117.91 1.03 128.30 66.88 30.38 48.70 175.82 20.37 204.43 30.14 116.02 0.20 128.62 68.19 30.47 49.19
70.36 30.29 49.37 BHT
chloroform
cyclohexane
1,2-dichloroethane dichloromethane diethyl ether diglyme
1,2-dimethoxyethane dimethylacetamide
dimethylformamide
dimethyl sulfoxide
dioxane ethanol ethyl acetate
ethyl methyl ketone ethylene glycol
“grease” n -hexane HMPA b
methanol
nitromethane n -pentane 2-propanol
pyridine
silicone grease
tetrahydrofuran toluene
triethylamine
C 72.87 C C H 3
26.99 C(1) 151.55 C(2) 135.87 CH(3) 125.55 C(4) 128.27 CH 3Ar 21.20 C H 3C 30.33 C 34.25 CH 77.36 CH 2 26.94 CH 2 43.50 CH 2 53.52 CH 3
15.20 CH 2
65.91 CH 3 59.01 CH 2
70.51 CH
2
71.90 CH 3 59.08 CH 2
71.84 CH 3 21.53 CO 171.07 NCH 3
35.28 NCH 3 38.13 CH 162.62 CH 3
36.50 CH 3 31.45 CH 3
40.76 CH 2 67.14 CH 3
18.41 CH 2
58.28 C H 3CO 21.04 CO 171.36 CH 2
60.49 CH
3
14.19 C H 3CO 29.49 CO 209.56 C H 2CH 3
36.89 CH 2C H 3 7.86 CH 2
63.79 CH 2 29.76 CH 3
14.14 CH 2(2) 22.70 CH 2(3) 31.64 CH 3 36.87 CH 3 50.41 CH 3 62.50 CH 3
14.08 CH 2(2) 22.38 CH 2(3) 34.16 CH 3 25.14 CH 64.50 CH(2) 149.90 CH(3) 123.75 CH(4) 135.96 CH 3
1.04 CH 2
25.62 CH 2O 67.97 CH 3 21.46 C(i ) 137.89 CH(o ) 129.07 CH(m ) 128.26 CH(p ) 125.33 CH 3 11.61 CH 2
46.25
72.81 72.04 27.24 26.79 152.51 151.47 138.19 139.12 129.05 127.97 126.03 124.85 21.31 20.97 31.61 31.25 35.00 34.33 79.19 79.16 27.51 26.33 45.25 45.02 54.95 54.84 15.78 15.12 66.12 62.05 58.77 57.98 71.03 69.54 72.63 71.25 58.45 58.01 72.47 17.07 21.51 21.29 170.61 169.54 34.89 37.38 37.92 34.42 162.79 162.29 36.15 35.73 31.03 30.73 41.23 40.45 67.60 66.36 18.89 18.51 57.72 56.07 20.83 20.68 170.96 170.31 60.56 59.74 14.50 14.40 29.30 29.26 208.30 208.72 36.75 35.83 8.03 7.61 64.26 62.76 30.73 29.20 14.34 13.88 23.28 22.05 32.30 30.95 37.04 36.42 49.77 48.59 63.21 63.28 14.29 13.28 22.98 21.70 34.83 33.48 25.67 25.43 63.85 64.92 150.67 149.58 124.57 123.84 136.56 136.05 1.40 26.15 25.14 68.07 67.03 21.46 20.99 138.48 137.35 129.76 128.88 129.03 128.18 126.12 125.29 12.49 11.74 47.07
45.74
72.40 73.17 27.09 27.28 152.05 152.42 136.08 138.13 128.52 129.61 125.83 126.38 21.40 21.23 31.34 31.50 34.35 35.05 77.79 79.17 27.23 27.63 43.59 45.54 53.46 55.32 15.46 15.63 65.94 66.32 58.66 58.90 70.87 70.99 72.35 72.63 58.68 58.89 72.21 72.47 21.16 21.76 169.95 171.31 34.67 35.17 37.03 38.26 162.13 163.31 35.25 36.57 30.72 31.32 40.03 41.31 67.16 67.72 18.72 18.80 57.86 57.96 20.56 21.16 170.44 171.68 60.21 60.98 14.19 14.54 28.56 29.60 206.55 209.88 36.36 37.09 7.91 8.14 64.34 64.22 30.21 30.86 14.32 14.43 23.04 23.40 31.96 32.36 36.88 37.10 49.97 49.90 61.16 63.66 14.25 14.37 22.72 23.08 34.45 34.89 25.18 25.55 64.23 64.30 150.27 150.76 123.58 127.76 135.28 136.89 1.38 25.72 26.27 67.80 68.33 21.10 21.50 137.91 138.90 129.33 129.94 128.56 129.23 125.68 126.28 12.35 12.38 46.77
47.10
74.32 75.62 27.22 26.60
152.85 139.09 129.49 126.11 21.38 31.15 35.36 79.44 27.96 45.11 54.78 15.46
14.77 66.88 66.42 59.06 58.67 71.33 70.05 72.92 71.63 59.06 58.67 72.72 71.49 21.32 21.09 173.32 174.57 35.50 35.03 38.43 38.76 164.73 165.53 36.89 37.54 31.61 32.03 40.45 39.39 68.11 67.19 18.40 17.47 58.26 58.05 20.88 21.15 172.89 175.26 61.50 62.32 14.49 13.92 29.39 29.49 212.16 218.43 37.34 37.27 8.09 7.87 64.30 63.17
31.29 14.45 23.68 32.73 37.00 36.46 49.86 49.50c 63.08 63.22
14.39 23.38 35.30 25.27
24.38 64.71 64.88 150.07 149.18 125.53 125.12 138.35 138.27 2.10 26.48 25.67 68.83 68.68
21.50 138.85 129.91 129.20 126.29 11.09
9.07 46.96
47.19